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Mössbauer Spectroscopy Vital Source e-bog
Virender K. Sharma, Gostar Klingelhofer og Tetsuaki Nishida
(2013)
Mössbauer Spectroscopy
Applications in Chemistry, Biology, and Nanotechnology
Virender K. Sharma, Gostar Klingelhofer og Tetsuaki Nishida
(2013)
Sprog: Engelsk
om ca. 10 hverdage
Detaljer om varen
- 1. Udgave
- Vital Source searchable e-book (Fixed pages): 672 sider
- Udgiver: John Wiley & Sons (September 2013)
- Forfattere: Virender K. Sharma, Gostar Klingelhofer og Tetsuaki Nishida
- ISBN: 9781118771907
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Detaljer om varen
- Hardback: 672 sider
- Udgiver: John Wiley & Sons, Incorporated (Oktober 2013)
- Forfattere: Virender K. Sharma, Gostar Klingelhofer og Tetsuaki Nishida
- ISBN: 9781118057247
Chapter 1 In-Situ Mössbauer Spectroscopy with Synchrotron Radiation on Thin Films 3 S Stankov, T slezak, M Zajac, M slezak, M Sladecek, R Röhlsberger, B. Sepiol, G Vogl, N Spiridis, J lazewski, K Parlioski, and J Korecki 1 1 Introduction 3
1.2 Instrumentation 4
1.3 Synchrotron radiation-based Mössbauer techniques 10 References 39
Chapter 2 Mössbauer Spectroscopy in Studying Electronic Spin and Valence States of Ironin the Earth''s Lower Mantle 43 Jung-Fu Lin, Zhu Mao, and Ercan E Alp
2.1 Introduction 43
2.2 Synchrotron Mössbauer Spectroscopy at High Pressures and Temperatures 44
2.3 Crystal Field Theory on the 3 d Electronic States 46
2.4 Conclusion 54 Acknowledgments 55 References 55
Chapter 3 In-beam Mössbauer Spectroscopy Using a Radioisotope Beam and a Neutron Capture Reaction 58 Yoshio Kobayashi
3.1 I ntroduction 58
3.2 57Mn (â?? 57Fe) Implantation Mössbauer Spectroscopy 61
3.3 Neutron in-beam Mössbauer Spectroscopy 66 3
.4 Summary 66 References 67
Part II Radionuclides 71
Chapter 4 Lanthanides(151Eu and 155Gd)-Mössbauer Spectroscopic Study of Defect-FluoriteOxides Coupled with New Defect-Crystal-Chemistry Model 73 Nakamura, N Igawa, Y Okamoto, Y Hinatsu, J, Wang, M Takahashi and M. Takeda
4.1 Introduction 73
4.2 Defect-crystal-Chemistry (DCC) Lattice-parameter Model 76
4.3 Lns Mössbauer and Lattice-parameter Data of DF Oxides 79
4.4 DCC-Model Lattice-parameter and Lns-Mössbauer Data Analysis 84 Conclusion 92 References 93
Chapter 5 Mössbauer and Magnetic Study of Neptunyl(+1) Complexes 95 T Nakamoto, A Nakamura and M Takeda
5.1 Introduction 95
5.2 237Np Mössbauer Spectroscopy 96
5.3 Magnetic Property of Neptunyl Monocation (NpO2+) 97
5.4 Mössbauer and Magnetic Study of Neptunyl(+1) Complexes 98
5.5 Discussion 106 Conclusion 113 Acknowledgment 113 References 113
Chapter 6 Mössbauer Spectroscopy of 161Dy in Dysprosium Dicarboxylates 116 M Takahashi, C I Wynter, B R Hillery, Virender K Sharma, D Quarless, Leopold May, T Misu, S G Sobel, M Takeda, and E Brown
6.1 Introduction 116
6.2 Experimental Methods 117
6.3 Results and Discussion 117 Acknowledgment 122 References 122
Chapter 7 Study of Exotic Uranium Compounds using 238U Mössbauer Spectroscopy 123 Satoshi Tsutsui1,2and Masami Nakada2
7.1 Introduction 123
7.2 Determination of Nuclear g -factor in the Excited State of 238U Nuclei 125
7.3 Application of 238U Mössbauer Spectroscopy to Heavy Fermion 127
7.4 Application to Two-dimensional (2D) Fermi Surface System of Uranium Dipnictides 134 Summary 137 Acknowledgment 138 References 138
Part III Spin Dynamics 141
Chapter 8 Reversible Spin-state Switching Involving a Structural Change 143 Satoru Nakashima
8.1 Introduction 143
8.2 Three Assembled Structures of Fe(NCX)2(bpa)2 (X=S, Se) and Their Structural Change by Desorption of Propanol Molecules 144
8.3 Occurrence of Spin-crossover Phenomenon in Assembled Complexes Fe(NCX)2(bpa)2 (X=S, Se, BH3) by Enclathrating Guest Molecules 145
8.4 Reversible Structural Change of Host Framework of Fe(NCS)2(bpp)2*2(benzene) Triggered By Sorption of Benzene Molecules 147
8.5 Reversible Spin-state Switching Involving a Structural Change of Fe(NCX)2(bpp)2*2(benzene) (X=Se, BH3) Triggered By Sorption of Benzene Molecules 149
8.6 Conclusion 150 References 151
Chapter 9 Spin- Crossover and Related Phenomena Coupled with Spin, Photon and Charge 152 N Kokima and A Sugahara
9.1 Introduction 152
9.2 Photo-induced Spin-crossover Phenomena 153 9 3 Charge Transfer Phase Transition 161 9 4 Spin Equilibrium and Succeeding Phenomena 168 References 175
Chapter 10 Spin Crossover in Iron(III) Porphyrins Involving the Intermediate-Spin State 177 Mikio Nakamura and Masashi Takahashi
10.1 Introduction 177
10.2 Methodology to Obtain Pure Intermediate-Spin Complexes 178
10.3 Spin Crossover Involving the Intermediate-Spin State 189
10.4 Spin Crossover Triangle in Iron(III) Porphyrins 195
10.5 Conclusion 198 Acknowledgments 198 References 199
Chapter 11 Tin(II) Lone Pair Stereoactivity: Influence on Structures and Properties, and Mössbauer Spectroscopic Properties 202 Georges Dénès, M Cecilia Madamba, Hocine Merazigand Abdualhafed Muntasar
11.1 Introduction 202
11.2 Experimental 203
11.3 Crystal Structures 204
11.4 Tin Electronic Structure and Mössbauer Spectroscopy 208
11.5 Application to the Structural Determination of 뱉??SnF2 213
11.6 Application to the Structural Determination of the Highly Layered Structures of 뱉??PbSnF4 and BaSnF4 216
11.7 Application to the Structural Study of Disordered Phases 226
11.8 Lone Pair Stereoactivity and Material Properties 241
11.9 Conclusion 242 Acknowledgments 243 References 243
Part IV Biological Applications 247
Chapter 12 Synchrotron Radiation Based Nuclear Resonant Scattering: Applications to Bioinorganic Chemistry 249 Yisong Guo, Yoshitaka Yoda, Xiaowei Zhang, Yuming Xiao, Stephen P Cram
12.1 Introduction 249
12.2 Technical Background 250
12.3 Applications in Bioinorganic Chemistry 258
12.4 Summary and Prospects 269 Acknowledgment 269 References 269
Chapter 13 Mössbauer Spectroscopy in Biological and Biomedical Research 272 Alexander A Kamnev1,*, Krisztina Kovács2, Irina V Alenkina3, and Michael I. Oshtrakh
13.1 Introduction 272
13.2 Microorganisms-related studies 273
13.3 Plants 276
13.4 Enzymes 280
13.5 Hemogoblin 281
13.6 Ferritin and Hemosiderin 283
13.7 Tissues 284
13.8 Pharmaceutical Products 286
13.9 Conclusions 286 Acknowledgments 287 References 287
Chapter 14 Controlled Spontaneous Decay of Mossbauer Nuclei (Theory and Experiments) 292 Vladimir I Vysotskii and Alla A Kornilova
14.1 Introduction to the Problem of Controlled Spontaneous Gamma-decay 292
14.2 General Consideration 293
14.3 Controlled Spontaneous Gamma-decay of Excited Nucleus in the System of Mutually Uncorrelated Modes of Electromagnetic Vacuum 295
14.4 Spontaneous Gamma-decay in the System of Synchronized Modes of Electromagnetic Vacuum 302
14.5 Experimental Study of the Phenomenon of Controlled Gamma-decay of Mossbauer Nuclei 303
14.6 Experimental Study of the Phenomenon of Controlled Gamma-decay by Investigation of Space Anisotropy and Self-focusing of Mossbauer Radiation 309
14.7 Direct Experimental Observation and Study of the Process of Controlled Radioactive and Excited Nuclei Radiative Gamma-decay by the Delayed Gamma-gamma Coincidence Method 311
14.8 Conclusion 314 References 314
Chapter 15 Natural''s Strategy to Oxidize Tryptophan: EPR and Mossbauer Characterization of High-Valent Fe Intermediates 315 Kednerlin Dornevil and Aimin Liu
15.1 Two Oxidizing Equivalents Stored at a Ferric Heme 315
15.2 Oxidation of L-Tryptophan by Heme-Based Enzymes 316
15.3 The Chemical Reaction Catalyzed by MauG 318
15.4 A High-Valent bis -Fe(IV) Intermediate in MauG 319
15.5 High-Valent Fe Intermediate of Tryptophan 2,3-Dioxygenase 319
15.6 Concluding Remarks 321 References 322
Chapter 16 Iron in Neurodegeneration 324 Jolanta Galazka-Friedman, Erika R Bauminger, and Andrzej Friedman
16.1 Introduction 324
16.2 Neurodegeneration and Oxidative Stress 324
16.3 Mössbauer Studies of Healthy Brain Tissue 325
16.4 Properties of Ferritin and Hemosiderin Present in Healthy Brain Tissue 327
16.5 Concentration of Iron Present in Healthy and Diseased Brain Issue 328
16.6 Asymmetry of the Mössbauer Spectra of Healthy and Diseased Brain Tissue 330
16.7 Conclusion - the Possible Role of Iron in Neurodegeneration 331 References 331
Chapter 17 Emission (57Co) Mössbauer Spectroscopy: Biology-related Applications, Potentials and Prospects 333 Alexander A Kamnev
17.1 Introduction 333
17.2 Methodology 334
17.3 Microbiological Applications 336
17.4 Enzymological Applications 340
17.5 Conclusions and Outlook 345 Acknowledgments 345 References 346
Part V Iron Oxides 349
Chapter 18 Mossbauer Spectroscopy in Study of Nanocrystalline Iron Oxides from Thermal Processes 351 Jirà Tucek, Libor Machala, Jirà Frydrych, Jirà Pechousek, and Radek Zboril
18.1 Introduction 351
18.2 Polymorphs of Iron (III) Oxide, Their Crystal Structures, Magnetic Properties, and Polymorphous Phase Transformations 352
18.3 Use of 57Fe Mössbauer Spectroscopy in Monitoring Solid State Reaction Mechanisms towards Iron Oxides 371
18.4 Various Mössbauer Spectroscopy Techniques in Study of Applications Related to Nanocrystalline Iron Oxides 378
18.5 Conclusion 389 Acknowled