SØG - mellem flere end 8 millioner bøger:
Viser: Chemical Vapour Deposition (CVD) - Advances, Technology and Applications
Søgbar e-bog
Chemical Vapour Deposition (CVD) Vital Source e-bog
Kwang-Leong Choy
(2019)
CRC Press
628,00 kr.
Leveres umiddelbart efter køb
Chemical Vapour Deposition (CVD)
Advances, Technology and Applications
Kwang-Leong Choy
(2019)
Sprog: Engelsk
CRC Press LLC
2.227,00 kr.
Print on demand. Leveringstid vil være ca 2-3 uger.
Detaljer om varen
- 1. Udgave
- Vital Source searchable e-book (Reflowable pages)
- Udgiver: CRC Press (Juni 2019)
- ISBN: 9781000691078
This book offers a timely and complete overview on chemical vapour deposition (CVD) and its variants for the processing of nanoparticles, nanowires, nanotubes, nanocomposite coatings, thin and thick films, and composites. Chapters discuss key aspects, from processing, material structure and properties to practical use, cost considerations, versatility, and sustainability. The author presents a comprehensive overview of CVD and its potential in producing high performance, cost-effective nanomaterials and thin and thick films. Features Provides an up-to-date introduction to CVD technology for the fabrication of nanomaterials, nanostructured films, and composite coatings Discusses processing, structure, functionalization, properties, and use in clean energy, engineering, and biomedical grand challenges Covers thin and thick films and composites Compares CVD with other processing techniques in terms of structure/properties, cost, versatility, and sustainability Kwang-Leong Choy is the Director of the UCL Centre for Materials Discovery and Professor of Materials Discovery in the Institute for Materials Discovery at the University College London. She earned her D.Phil. from the University of Oxford, and is the recipient of numerous honors including the Hetherington Prize, Oxford Metallurgical Society Award, and Grunfeld Medal and Prize from the Institute of Materials (UK). She is an elected fellow of the Institute of Materials, Minerals and Mining, and the Royal Society of Chemistry.
Licens varighed:
Bookshelf online: 5 år fra købsdato.
Bookshelf appen: ubegrænset dage fra købsdato.
Udgiveren oplyser at følgende begrænsninger er gældende for dette produkt:
Print: 2 sider kan printes ad gangen
Copy: højest 2 sider i alt kan kopieres (copy/paste)
Bookshelf online: 5 år fra købsdato.
Bookshelf appen: ubegrænset dage fra købsdato.
Udgiveren oplyser at følgende begrænsninger er gældende for dette produkt:
Print: 2 sider kan printes ad gangen
Copy: højest 2 sider i alt kan kopieres (copy/paste)
Detaljer om varen
- Hardback: 398 sider
- Udgiver: CRC Press LLC (Marts 2019)
- ISBN: 9781466597761
This book offers a timely and complete overview on chemical vapour deposition (CVD) and its variants for the processing of nanoparticles, nanowires, nanotubes, nanocomposite coatings, thin and thick films, and composites. Chapters discuss key aspects, from processing, material structure and properties to practical use, cost considerations, versatility, and sustainability. The author presents a comprehensive overview of CVD and its potential in producing high performance, cost-effective nanomaterials and thin and thick films.
Features
- Provides an up-to-date introduction to CVD technology for the fabrication of nanomaterials, nanostructured films, and composite coatings
- Discusses processing, structure, functionalization, properties, and use in clean energy, engineering, and biomedical grand challenges
- Covers thin and thick films and composites
- Compares CVD with other processing techniques in terms of structure/properties, cost, versatility, and sustainability
Kwang-Leong Choy is the Director of the UCL Centre for Materials Discovery and Professor of Materials Discovery in the Institute for Materials Discovery at the University College London. She earned her D.Phil. from the University of Oxford, and is the recipient of numerous honors including the Hetherington Prize, Oxford Metallurgical Society Award, and Grunfeld Medal and Prize from the Institute of Materials (UK). She is an elected fellow of the Institute of Materials, Minerals and Mining, and the Royal Society of Chemistry.
Contents Preface xiii Editor xv Contributors xvii 1 Introduction Kwang Leong Choy and Cigang Xu
1.1 Chemical vapour deposition: Fundamentals and process principles 1
1.1.1 Definition 1
1.1.2 A brief history and development of CVD 2
1.1.3 Fundamentals and process principles 4
1.1.3.1 Thermodynamics/kinetics/mass transport of CVD 4
1.1.3.2 CVD precursors delivery, properties, and chemistry 8
1.1.3.3 CVD process parameters and control/monitoring to ensure reliability and reproducibility 12
1.2 Advances in CVD deposition technologies, growth of materials and applications 14
1.2.1 Large-area and high-volume production 15
1.2.2 Multiple functions 15
1.2.3 New materials and processes 15
1.3 Variant vacuum CVD methods 17
1.3.1 Vacuum-based methods 17
1.3.1.1 Plasma-enhanced CVD 17
1.3.1.2 Microwave-assisted CVD 20
1.3.1.3 Metalorganic CVD 23
1.3.1.4 Molecular-beam epitaxy 28
1.3.1.5 Chemical-beam epitaxy 34
1.3.1.6 Atomic layer deposition 37
1.3.1.7 Energetic ion-assisted CVD 43
1.3.1.8 Laser/photo-assisted CVD 49
1.3.2 Non-vacuum methods 51
1.3.2.1 Atmospheric pressure CVD 51
1.3.2.2 Atmospheric pressure MOCVD 58
1.3.2.3 Aerosol-assisted CVD 58
1.3.2.4 Electrostatic spray-assisted vapour deposition 62
1.3.2.5 Flame-assisted CVD 69
1.4 CVD of polymers 71
1.5 CVD modelling and simulation 76
1.6 CVD and its variants as tools for processing advanced materials to address energy, engineering, and biomedical grand challenges 80
1.6.1 Energy 80
1.6.2 Engineering 81
1.6.3 Biomedical 82
1.7 Advantages and limitations of CVD 83
1.8 Comparison of CVD with other processing techniques
: Structure, properties, cost, sustainability, and versatility 84
1.9 Summary 89 Acknowledgement 89 References 89 2 Chemical vapour deposition of ultrafine particles 105 Cigang Xu and Kwang Leong Choy
2.1 Introduction 105
2.2 Processing, formation mechanism, structure, and properties 107
2.2.1 Processing methods using solid precursors 108
2.2.1.1 Condensation method 108
2.2.1.2 Laser-ablation method 109
2.2.1.3 Arc-discharge method 111
2.2.1.4 Reactive sputtering method 114
2.2.1.5 Ion-beam-based method 116
2.2.2 Processing methods using liquid or vapour precursors 119
2.2.2.1 Thermal CVD method 119
2.2.2.2 MOCVD method 120
2.2.2.3 Spray pyrolysis/ aerosol-assisted CVD 122
2.2.2.4 Flame synthesis 124
2.2.2.5 Flame spray pyrolysis 124
2.2.2.6 Laser pyrolysis 127
2.2.2.7 Plasma-based synthesis 128
2.2.2.8 MBE method 129
2.2.2.9 Ionisation method 131
2.2.2.10 Atomic layer deposition 131
2.2.3 Scale-up production 136
2.3 Scientific and technical issues and process control for producing high-performance nanoparticles for applications in structural, clean energy, biomedical, and environmental sectors 141
2.3.1 Structural applications 141
2.3.2 Clean energy 142
2.3.3 Biomedical applications 143
2.3.4 Environmental 144
2.4 Summary 146 References 146 3 CVD of nanowires and nanotubes, mass production, and industrialization 153 Cigang Xu and Kwang Leong Choy
3.1 Introduction 153
3.2 Preparation, structure, properties and applications of nanostructures 155
3.2.1 Carbon nanotubes 155
3.2.2 Si and Ge nanowires 166
3.2.3 III-V 1D nanomaterials 168
3.2.4 II-VI 1D nanomaterials 170
3.2.5 Oxides 171
3.2.6 Carbides 175
3.2.7 Nitrides 179
3.2.8 Elemental nanowires 184
3.2.9 Complex structures of 1D nanomaterial 185
3.2.10 Structural applications 196
3.2.11 Clean energy applications 197
3.2.12 Biomedical applications 200
3.2.13 Environmental applications 202
3.3 Scale-up prototype production and industrialization of nanowires and nanotubes 204
3.3.1 Scale-up prototype production of nanowires and nanotubes 204
3.3.1.1 Carbon nanotubes 204
3.3.1.2 Multi-walled carbon nanotubes 205
3.3.1.3 Bush-style MWNTs 207
3.3.1.4 Double-walled carbon nanotubes 207
3.3.1.5 Single-walled carbon nanotubes 211
3.3.1.6 Bush-style SWNTs 215
3.3.1.7 Other 1D materials 216
3.3.2 Industrialization of nanotubes 217
3.3.2.1 Industrialisation of multi-walled carbon nanotubes 218
3.3.2.2 Industrialisation of single-walled carbon nanotubes 221
3.3.2.3 Environment, health, and safety issues 223
3.3.2.4 Summary and outlook 224 References 225 4 CVD of flat monolayer of 2D atomics honeycomb structure and their applications 245 Manoj Kumar Singh, Dhananjay K. Sharma, Gonzalo Otero-Irurueta and María J. Hortigüela
4.1 Introduction 245
4.2 Graphene 246
4.2.1 Electronic structure of single-layer graphene 246
4.2.2 Graphene properties and synthesis 248
4.2.2.1 Graphene on single crystals grown under UHV conditions 248
4.2.2.2 Liquid phase exfoliation 249
4.2.2.3 Graphene on silicon carbide 250
4.2.2.4 Graphene by state-of-the-art technique chemical vapour deposition 252
4.2.3 From the laboratory to the industry 253
4.2.4 Quality comparison 257
4.2.5 Doping of graphene 258
4.3 Silicene 259
4.3.1 Electronic structure of silicene 260
4.3.2 Synthesis of silicene on surfaces 260
4.3.2.1 First synthesis of silicene on silver substrates 260
4.3.2.2 Silicene on other substrates 262
4.3.3 Controversy - discrepancies 262
4.3.4 From the laboratory to the industry 263
4.4 Germanene 263
4.4.1 Electronic structure of germanene 264
4.4.2 First synthesis of germanene on gold 265
4.4.3 Germanene on platinum 265
4.5 Conclusions 266 References 267 5 CVD of superlattice films and their applications 273 Guillaume Savelli
5.1 Introduction 273
5.1.1 Definitions 273
5.1.2 Superlattice band structures 274
5.1.3 Superlattices deposition techniques 275
5.2 CVD processing, deposition mechanisms, and structures 275
5.2.1 Superlattices processing steps 277
5.2.2 QWSL and QDSL deposition mechanisms 278
5.2.3 QWSL and QDSL structures 280
5.3 Main QWSL and QDSL properties 282
5.3.1 Mechanical properties 282
5.3.2 Electrical properties 282
5.3.3 Optical properties 283
5.3.4 Thermal properties 284
5.4 Applications 285
5.4.1 Photonics 285
5.4.1.1 Solar cells 286
5.4.1.2 Avalanche photodiodes 286
5.4.1.3 Inter-sub-band detectors 287
5.4.1.4 VCSEL 287
5.4.2 Optoelectronics 288
5.4.3 Thermoelectrics 288
5.4.4 Future prospects 290 References 291 6 CVD coatings 295 Kwang Leong Choy
6.1 Advanced protective coatings for cutting tools 295
6.2 Thermal barrier coatings (TBCS) 300
6.2.1 Conventional thermally assisted CVD 301
6.2.2 Plasma-assisted CVD 301
6.2.3 Laser-assisted CVD 301
6.2.4 Electrostatic spray-assisted vapour deposition (ESAVD) 303
6.3 Diffusion coatings 304
6.4 Thick silicon coatings 306
6.5 Thick metal coatings 307
6.6 Polymeric coatings 308
6.6.1 Applications 309
6.7 Fibre coatings and ceramic monofilament fibre production 311
6.7.1 Boron fibres 311
6.7.2 SiC fibres 313
6.7.3 Applications 314
6.8 Optical fibres 316
6.9 Free-standing shapes and 3D deposition 317
6.9.1 Thin free-standing foils and membranes 319
6.9.2 Thick disks and wafers 319
6.9.3 Near net-shape free-standing shaped articles 323
6.9.4 Free-standing micro-objects 324 Acknowledgement 325 References 325 7 CVD of nanocomposite coatings 331 Yuri Zhuk and Kwang Leong Choy
7.1 Thermal CVD of nanostructured tungsten carbide-based nanocomposite coatings 331
7.1.1 Background 331
7.1.2 Coating deposition method, structure, and composition 332
7.1.2.1 Coating deposition method 332
7.1.2.2 Nano-structure of Hardide coatings 332
7.1.2.3 Types of Hardide coatings and their composition 334
7.1.3 Benefits of the coating nanostructure 335
7.1.3.1 Combination of high hardness with enhanced toughness and resistance to impact and deformations 335
7.1.3.2 Coating retaining surface finish after operation in abrasive and corrosive conditions 338
7.1.3.3 Absence of porosity and corrosion-protective properties of Hardide coating 339
7.1.3.4 Enhanced wear and erosion resistance of Hardide coatings 341
7.1.4 Examples of Hardide nanocomposite coating applications 343
7.1.4.1 Coating complex shapes and internal surfaces 343
7.1.4.2 Coating severe-service ball valves and their performance 344
7.1.4.3 Applications with oil drilling and downhole tools 345
7.1.4.4 Applications in pumps 345
7.1.4.5 Hardide as a hard chrome replacement 346
7.1.5 Summary 346
7.2 PECVD and LPCVD of hard/superhard ternary and quaternary nanocomposite coatings 346
7.3 A hybrid PVD and CVD of hard nanocomposite films 349
7.3.1 Single-layer nanocomposite film 349
7.3.2 Multilayered nanocomposite coatings 350
7.4 Laser-assisted CVD of oxide-based nanocomposite films 351
7.5 Sequential CVD deposition of oxide-based nanocomposite films 351
7.6 AACVD of oxide-based nanocomposite films and coatings 352
7.6.1 AACVD of Au in transit
1.1 Chemical vapour deposition: Fundamentals and process principles 1
1.1.1 Definition 1
1.1.2 A brief history and development of CVD 2
1.1.3 Fundamentals and process principles 4
1.1.3.1 Thermodynamics/kinetics/mass transport of CVD 4
1.1.3.2 CVD precursors delivery, properties, and chemistry 8
1.1.3.3 CVD process parameters and control/monitoring to ensure reliability and reproducibility 12
1.2 Advances in CVD deposition technologies, growth of materials and applications 14
1.2.1 Large-area and high-volume production 15
1.2.2 Multiple functions 15
1.2.3 New materials and processes 15
1.3 Variant vacuum CVD methods 17
1.3.1 Vacuum-based methods 17
1.3.1.1 Plasma-enhanced CVD 17
1.3.1.2 Microwave-assisted CVD 20
1.3.1.3 Metalorganic CVD 23
1.3.1.4 Molecular-beam epitaxy 28
1.3.1.5 Chemical-beam epitaxy 34
1.3.1.6 Atomic layer deposition 37
1.3.1.7 Energetic ion-assisted CVD 43
1.3.1.8 Laser/photo-assisted CVD 49
1.3.2 Non-vacuum methods 51
1.3.2.1 Atmospheric pressure CVD 51
1.3.2.2 Atmospheric pressure MOCVD 58
1.3.2.3 Aerosol-assisted CVD 58
1.3.2.4 Electrostatic spray-assisted vapour deposition 62
1.3.2.5 Flame-assisted CVD 69
1.4 CVD of polymers 71
1.5 CVD modelling and simulation 76
1.6 CVD and its variants as tools for processing advanced materials to address energy, engineering, and biomedical grand challenges 80
1.6.1 Energy 80
1.6.2 Engineering 81
1.6.3 Biomedical 82
1.7 Advantages and limitations of CVD 83
1.8 Comparison of CVD with other processing techniques
: Structure, properties, cost, sustainability, and versatility 84
1.9 Summary 89 Acknowledgement 89 References 89 2 Chemical vapour deposition of ultrafine particles 105 Cigang Xu and Kwang Leong Choy
2.1 Introduction 105
2.2 Processing, formation mechanism, structure, and properties 107
2.2.1 Processing methods using solid precursors 108
2.2.1.1 Condensation method 108
2.2.1.2 Laser-ablation method 109
2.2.1.3 Arc-discharge method 111
2.2.1.4 Reactive sputtering method 114
2.2.1.5 Ion-beam-based method 116
2.2.2 Processing methods using liquid or vapour precursors 119
2.2.2.1 Thermal CVD method 119
2.2.2.2 MOCVD method 120
2.2.2.3 Spray pyrolysis/ aerosol-assisted CVD 122
2.2.2.4 Flame synthesis 124
2.2.2.5 Flame spray pyrolysis 124
2.2.2.6 Laser pyrolysis 127
2.2.2.7 Plasma-based synthesis 128
2.2.2.8 MBE method 129
2.2.2.9 Ionisation method 131
2.2.2.10 Atomic layer deposition 131
2.2.3 Scale-up production 136
2.3 Scientific and technical issues and process control for producing high-performance nanoparticles for applications in structural, clean energy, biomedical, and environmental sectors 141
2.3.1 Structural applications 141
2.3.2 Clean energy 142
2.3.3 Biomedical applications 143
2.3.4 Environmental 144
2.4 Summary 146 References 146 3 CVD of nanowires and nanotubes, mass production, and industrialization 153 Cigang Xu and Kwang Leong Choy
3.1 Introduction 153
3.2 Preparation, structure, properties and applications of nanostructures 155
3.2.1 Carbon nanotubes 155
3.2.2 Si and Ge nanowires 166
3.2.3 III-V 1D nanomaterials 168
3.2.4 II-VI 1D nanomaterials 170
3.2.5 Oxides 171
3.2.6 Carbides 175
3.2.7 Nitrides 179
3.2.8 Elemental nanowires 184
3.2.9 Complex structures of 1D nanomaterial 185
3.2.10 Structural applications 196
3.2.11 Clean energy applications 197
3.2.12 Biomedical applications 200
3.2.13 Environmental applications 202
3.3 Scale-up prototype production and industrialization of nanowires and nanotubes 204
3.3.1 Scale-up prototype production of nanowires and nanotubes 204
3.3.1.1 Carbon nanotubes 204
3.3.1.2 Multi-walled carbon nanotubes 205
3.3.1.3 Bush-style MWNTs 207
3.3.1.4 Double-walled carbon nanotubes 207
3.3.1.5 Single-walled carbon nanotubes 211
3.3.1.6 Bush-style SWNTs 215
3.3.1.7 Other 1D materials 216
3.3.2 Industrialization of nanotubes 217
3.3.2.1 Industrialisation of multi-walled carbon nanotubes 218
3.3.2.2 Industrialisation of single-walled carbon nanotubes 221
3.3.2.3 Environment, health, and safety issues 223
3.3.2.4 Summary and outlook 224 References 225 4 CVD of flat monolayer of 2D atomics honeycomb structure and their applications 245 Manoj Kumar Singh, Dhananjay K. Sharma, Gonzalo Otero-Irurueta and María J. Hortigüela
4.1 Introduction 245
4.2 Graphene 246
4.2.1 Electronic structure of single-layer graphene 246
4.2.2 Graphene properties and synthesis 248
4.2.2.1 Graphene on single crystals grown under UHV conditions 248
4.2.2.2 Liquid phase exfoliation 249
4.2.2.3 Graphene on silicon carbide 250
4.2.2.4 Graphene by state-of-the-art technique chemical vapour deposition 252
4.2.3 From the laboratory to the industry 253
4.2.4 Quality comparison 257
4.2.5 Doping of graphene 258
4.3 Silicene 259
4.3.1 Electronic structure of silicene 260
4.3.2 Synthesis of silicene on surfaces 260
4.3.2.1 First synthesis of silicene on silver substrates 260
4.3.2.2 Silicene on other substrates 262
4.3.3 Controversy - discrepancies 262
4.3.4 From the laboratory to the industry 263
4.4 Germanene 263
4.4.1 Electronic structure of germanene 264
4.4.2 First synthesis of germanene on gold 265
4.4.3 Germanene on platinum 265
4.5 Conclusions 266 References 267 5 CVD of superlattice films and their applications 273 Guillaume Savelli
5.1 Introduction 273
5.1.1 Definitions 273
5.1.2 Superlattice band structures 274
5.1.3 Superlattices deposition techniques 275
5.2 CVD processing, deposition mechanisms, and structures 275
5.2.1 Superlattices processing steps 277
5.2.2 QWSL and QDSL deposition mechanisms 278
5.2.3 QWSL and QDSL structures 280
5.3 Main QWSL and QDSL properties 282
5.3.1 Mechanical properties 282
5.3.2 Electrical properties 282
5.3.3 Optical properties 283
5.3.4 Thermal properties 284
5.4 Applications 285
5.4.1 Photonics 285
5.4.1.1 Solar cells 286
5.4.1.2 Avalanche photodiodes 286
5.4.1.3 Inter-sub-band detectors 287
5.4.1.4 VCSEL 287
5.4.2 Optoelectronics 288
5.4.3 Thermoelectrics 288
5.4.4 Future prospects 290 References 291 6 CVD coatings 295 Kwang Leong Choy
6.1 Advanced protective coatings for cutting tools 295
6.2 Thermal barrier coatings (TBCS) 300
6.2.1 Conventional thermally assisted CVD 301
6.2.2 Plasma-assisted CVD 301
6.2.3 Laser-assisted CVD 301
6.2.4 Electrostatic spray-assisted vapour deposition (ESAVD) 303
6.3 Diffusion coatings 304
6.4 Thick silicon coatings 306
6.5 Thick metal coatings 307
6.6 Polymeric coatings 308
6.6.1 Applications 309
6.7 Fibre coatings and ceramic monofilament fibre production 311
6.7.1 Boron fibres 311
6.7.2 SiC fibres 313
6.7.3 Applications 314
6.8 Optical fibres 316
6.9 Free-standing shapes and 3D deposition 317
6.9.1 Thin free-standing foils and membranes 319
6.9.2 Thick disks and wafers 319
6.9.3 Near net-shape free-standing shaped articles 323
6.9.4 Free-standing micro-objects 324 Acknowledgement 325 References 325 7 CVD of nanocomposite coatings 331 Yuri Zhuk and Kwang Leong Choy
7.1 Thermal CVD of nanostructured tungsten carbide-based nanocomposite coatings 331
7.1.1 Background 331
7.1.2 Coating deposition method, structure, and composition 332
7.1.2.1 Coating deposition method 332
7.1.2.2 Nano-structure of Hardide coatings 332
7.1.2.3 Types of Hardide coatings and their composition 334
7.1.3 Benefits of the coating nanostructure 335
7.1.3.1 Combination of high hardness with enhanced toughness and resistance to impact and deformations 335
7.1.3.2 Coating retaining surface finish after operation in abrasive and corrosive conditions 338
7.1.3.3 Absence of porosity and corrosion-protective properties of Hardide coating 339
7.1.3.4 Enhanced wear and erosion resistance of Hardide coatings 341
7.1.4 Examples of Hardide nanocomposite coating applications 343
7.1.4.1 Coating complex shapes and internal surfaces 343
7.1.4.2 Coating severe-service ball valves and their performance 344
7.1.4.3 Applications with oil drilling and downhole tools 345
7.1.4.4 Applications in pumps 345
7.1.4.5 Hardide as a hard chrome replacement 346
7.1.5 Summary 346
7.2 PECVD and LPCVD of hard/superhard ternary and quaternary nanocomposite coatings 346
7.3 A hybrid PVD and CVD of hard nanocomposite films 349
7.3.1 Single-layer nanocomposite film 349
7.3.2 Multilayered nanocomposite coatings 350
7.4 Laser-assisted CVD of oxide-based nanocomposite films 351
7.5 Sequential CVD deposition of oxide-based nanocomposite films 351
7.6 AACVD of oxide-based nanocomposite films and coatings 352
7.6.1 AACVD of Au in transit
De oplyste priser er inkl. moms
Butikker og åbningstid
Handler du som firma
Forretningsbetingelser
Porto og forsendelse
Data & cookiepolitik
Handler du som firma
Forretningsbetingelser
Porto og forsendelse
Data & cookiepolitik
Polyteknisk Boghandel og Forlag A/S - Anker Engelundsvej 1 - 2800 Lyngby
Tlf 77 42 43 44 - email poly@polyteknisk.dk - CVR 34072655 - Sydbank Reg: 6748 Konto 0001107927
Tlf 77 42 43 44 - email poly@polyteknisk.dk - CVR 34072655 - Sydbank Reg: 6748 Konto 0001107927