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Viser: Organic Chemistry - Pearson New International Edition

Organic Chemistry - Pearson New International Edition, 7. udgave

Organic Chemistry

Pearson New International Edition
Paula Y. Bruice
(2013)
Sprog: Engelsk
Pearson Education, Limited
770,00 kr.
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Denne bog er blevet erstattet af Organic Chemistry, Global Edition, 8. udgave

Detaljer Om Varen

  • 7. Udgave
  • Paperback: 1344 sider
  • Udgiver: Pearson Education, Limited (Juli 2013)
  • ISBN: 9781292024363
All of Paula Bruice's extensive revisions to the Seventh Edition of Organic Chemistry follow a central guiding principle: support what modern students need in order to understand and retain what they learn in organic chemistry for successful futures in industry, research, and medicine. In consideration of today's classroom dynamics and the changes coming to the 2015 MCAT, this revision offers a completely new design with enhanced art throughout, reorganization of materials to reinforce fundamental skills and facilitate more efficient studying.

Part 1 An Introduction to the Study of Organic Chemistry 1 Remembering General Chemistry: Electronic Structure and Bonding
1.
1 The Structure of an Atom
1.
2 How the Electrons in an Atom Are Distributed
1.
3 Ionic and Covalent Bonds
1.
4 How the Structure of a Compound Is Represented
1.
5 Atomic Orbitals
1.
6 An Introduction to Molecular Orbital Theory
1.
7 How Single Bonds Are Formed in Organic Compounds
1.
8 How a Double Bond Is Formed: The Bonds in Ethene
1.
9 How a Triple Bond Is Formed: The Bonds in Ethyne
1.
10 The Bonds in the Methyl Cation, the Methyl Radical, and the Methyl Anion
1.
11 The Bonds in Ammonia and In the Ammonium Ion
1.
12 The Bonds in Water
1.
13 The Bond in a Hydrogen Halide
1.
14 Hybridization and Molecular Geometry
1.
15 Summary: Hybridization, Bond Lengths, Bond Strengths, and Bond Angles
1.
16 The Dipole Moments of Molecules 2 Acids and Bases: Central to Understanding Organic Chemistry
2.
1 An Introduction to Acids and Bases
2.
2 pka and pH
2.
3 Organic Acids and Bases
2.
4 How to Predict the Outcome of an Acid--Base Reaction
2.
5 How to Determine the Position of Equilibrium
2.
6 How the Structure of an Acid affects its pKa Value
2.
7 How Substituent''s affect the Strength of an Acid
2.
8 An Introduction to Delocalized Electrons
2.
9 A Summary of the Factors That Determine Acid Strength
2.
10 How pH affects the Structure of an Organic Compound
2.
11 Buffer Solutions
2.
12 Lewis Acids and Bases Tutorial: Acids and Bases 3 An Introduction to Organic Compounds: Nomenclature, Physical Properties, and Representation of Structure
3.
1 How Alkyl Substituents Are Named
3.
2 The Nomenclature of Alkanes
3.
3 The Nomenclature of Cycloalkanes * Skeletal Structures
3.
4 The Nomenclature of Alkyl Halides
3.
5 The Nomenclature of Ethers
3.
6 The Nomenclature of Alcohols
3.
7 The Nomenclature of Amines
3.
8 The Structures of Alkyl Halides, Alcohols, Ethers, and Amines
3.
9 The Physical Properties of Alkanes, Alkyl Halides, Alcohols, Ethers, and Amines
3.
10 Rotation Occurs about Carbon--Carbon single Bonds
3.
11 Some Cycloalkanes Have Angle Strain
3.
12 The Conformers of Cyclohexane
3.
13 Conformers of Monosubstituted Cyclohexanes
3.
14 Conformers of Disubstituted Cyclohexanes
3.
15 Fused Cyclohexane Rings

Part Two Electrophilic Addition Reactions, Stereochemistry, and Electron Delocalization Tutorial: Using Molecular Models 4 Isomers: The Arrangement of Atoms in Space
4.
1 Cis--Trans Isomers Result from Restricted Rotation
4.
2 A Chiral Object Has a Nonsuperimposable Mirror Image
4.
3 An Asymmetric Center is a Cause of Chirality in a Molecule
4.
4 Isomers with One Asymmetric Center
4.
5 Asymmetric Centers and Stereocenters
4.
6 How to Draw Enantiomers
4.
7 Naming Enantiomers by the R, S System
4.
8 Chiral Compounds Are Optically Active
4.
9 How Specific Rotation Is Measured
4.
10 Enantiomeric Excess
4.
11 Compounds with More than One Asymmetric Center
4.
12 Stereoisomers of Cyclic Compounds
4.
13 Meso Compounds Have Asymmetric Centers but Are Optically Inactive
4.
14 How to Name Isomers with More than One Asymmetric Center
4.
15 How Enantiomers Can be Separated
4.
16 Nitrogen and Phosphorus Atoms Can Be Asymmetric Centers Tutorial: Interconverting Structural Representations 5 Alkenes: Structure, Nomenclature, and an Introduction to Reactivity * Thermodynamics and Kinetics
5.
1 Molecular Formulas and the Degree of Unsaturation
5.
2 The Nomenclature of Alkenes
5.
3 The Structure of Alkenes
5.
4 Naming Alkenes Using the E,Z System
5.
5 How an Organic Compound Reacts Depends On Its Functional Group
5.
6 How Alkenes React * Curved Arrows Show the Flow of Electrons
5.
7 Thermodynamics and Kinetics
5.
8 The Rate of a Chemical Reaction
5.
9 The Difference between the Rate of a Reaction and the Rate Constant for a Reaction
5.
10 A Reaction Coordinate Diagram Describes the Energy Changes that Take Place during a Reaction
5.
11 Catalysis
5.
12 Catalysis by Enzymes Tutorial: An Exercise in Drawing Curved Arrows: Pushing Electrons 6 The Reactions of Alkenes: The Stereochemistry of Addition Reactions
6.
1 The Addition of a Hydrogen Halide to an Alkene
6.
2 Carbocation Stability Depends on the Number of Alkyl Groups Attached to the Positively Charged Carbon
6.
3 What Does the Structure of the Transition State Look Like?
6.
4 Electrophilic Addition Reactions Are Regioselective
6.
5 The Addition of Water to an Alkene
6.
6 The Addition of an Alcohol to an Alkene
6.
7 A Carbocation will rearrange if it can Form a More Stable Carbocation
6.
8 Oxymercuration--Demercuration Is another Way to Add Water to an Alkene
6.
9 The Addition of Borane to an Alkene: Hydroboration--Oxidation
6.
10 The Addition of a Halogen to an Alkene
6.
11 The Addition of a Peroxyacid to an Alkene
6.
12 The Addition Of Ozone To An Alkene: Ozonolysis
6.
13 The Addition of Hydrogen to an Alkene
6.
14 The Relative Stabilities of Alkenes
6.
15 Regioselective, Stereoselective, and Stereospecific Reactions
6.
16 The Stereochemistry of Electrophilic Addition Reactions of Alkenes
6.
17 The Stereochemistry of Enzyme-Catalyzed Reactions
6.
18 Enantiomers Can Be Distinguished by Biological Molecules
6.
19 Reactions and Synthesis 7 The Reactions of Alkynes: An Introduction to Multistep Synthesis
7.
1 The Nomenclature of Alkynes
7.
2 How to Name a Compound That Has More than One Functional Group
7.
3 The Physical Properties of Unsaturated Hydrocarbons
7.
4 The Structure of Alkynes
7.
5 Alkynes Are Less Reactive than Alkenes
7.
6 The Addition of Hydrogen Halides and the Addition of Halogens to an Alkyne
7.
7 The Addition of Water to an Alkyne
7.
8 The Addition of Borane to an Alkyne: Hydroboration--Oxidation
7.
9 The Addition of Hydrogen to an Alkyne
7.
10 A Hydrogen Bonded to an sp Carbon Is "Acidic"
7.
11 Synthesis Using Acetylide Ions
7.
12 Designing a Synthesis
I: An Introduction to Multistep Synthesis 8 Delocalized Electrons and Their Effect on Stability, p K a, and the Products of a Reaction
8.
1 Delocalized Electrons Explain Benzene''s Structure
8.
2 The Bonding in Benzene
8.
3 Resonance Contributors and the Resonance Hybrid
8.
4 How to Draw Resonance Contributors
8.
5 The Predicted Stabilities of Resonance Contributors
8.
6 Delocalization Energy Is the Additional Stability Delocalized Electrons Give to a Compound
8.
7 Benzene is an Aromatic Compound
8.
8 The Two Criteria for Aromaticity
8.
9 Applying the Criteria for Aromaticity
8.
10 Aromatic Heterocyclic Compounds
8.
11 Antiaromaticity
8.
12 A Molecular Orbital Description of Aromaticity and Antiaromaticity
8.
13 More Examples that Show How Delocalized Electrons Affect Stability
8.
14 A Molecular Orbital Description of Stability
8.
15 How Delocalized Electrons Affect p K a Values
8.
16 Delocalized Electrons Can Affect the Product of a Reaction
8.
17 Reactions of Dienes
8.
18 Thermodynamic Versus Kinetic Control
8.
19 The Diels--Alder Reaction Is a 1,4-Addition Reaction
8.
20 Retrosynthetic Analysis of the Diels--Alder Reaction
8.
21 Organizing What We Know About the Reactions of Organic Compounds Tutorial: Drawing Resonance Contributors

Part Three Substitution and Elimination Reactions 9 Substitution Reactions of Alkyl Halides
9.
1 The Mechanism for an SN2 Reaction
9.
2 Factors That Affect SN2 Reactions
9.
3 The Mechanism for an SN1 Reaction
9.
4 Factors That Affect SN1 Reactions
9.
5 Benzylic Halides, Allylic Halides, Vinylic Halides, and Aryl Halides
9.
6 Competition between SN2 and SN1 Reactions
9.
7 The Role of the Solvent in SN1 and SN2 Reactions
9.
8 Intermolecular Versus Intramolecular Reactions
9.
9 Methylating Agents Used by Chemists Versus Those Used by Cells 10 Elimination Reactions of Alkyl Halides * Competition between Substitution and Elimination
10.
1 The E2 Reaction
10.
2 An E2 Reaction Is Regioselective
10.
3 The E1 Reaction
10.
4 Benzylic and Allylic Halides
10.
5 Competition between E2 and E1 Reactions
10.
6 E2 and E1 Reactions Are Stereoselective
10.
7 Elimination from Substituted Cyclohexanes
10.
8 A Kinetic Isotope Effect Can Help Determine a Mechanism
10.
9 Competition between Substitution and Elimination
10.
10 Substitution and Elimination Reactions in Synthesis
10.
11 Designing a Synthesis
II: Approaching the Problem 11 Reactions of Alcohols, Ethers, Amines, Thiols, and Thioethers
11.
1 Nucleophilic Substitution Reactions of Alcohols: Forming Alkyl Halides
11.
2 Other Methods used to Convert Alcohols into Alkyl Halides
11.
3 Converting an Alcohol into a Sulfonate Ester
11.
4 Elimination Reactions of Alcohols: Dehydration
11.
5 Oxidation of Alcohols
11.
6 Nucleophilic Substitution Reactions of Ethers
11.
7 Nucleophilic Substitution Reactions of Epoxides
11.
8 Arene Oxides
11.
9 Amines do not Undergo Substitution or Elimination Reactions
11.
10 Quaternary Ammonium Hydroxides Undergo Elimination Reactions
11.
11 Thiols, Sulfides, and Sulfonium Salts
11.
12 Organizing What We Know About the Reactions of Orga
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