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Viser: Molybdenum and Tungsten Enzymes - Spectroscopic and Theoretical Investigations
Molybdenum and Tungsten Enzymes Vital Source e-bog
Vadim Gladyshev
(2016)
Molybdenum and Tungsten Enzymes
Spectroscopic and Theoretical Investigations
Russ Hille, Carola Schulzke og Martin L. Kirk
(2016)
Sprog: Engelsk
om ca. 10 hverdage
Detaljer om varen
- 1. Udgave
- Vital Source searchable e-book (Fixed pages)
- Udgiver: NBN International (Oktober 2016)
- ISBN: 9781782628842
There has been enormous progress in our understanding of molybdenum and tungsten enzymes and relevant inorganic complexes of molybdenum and tungsten over the past twenty years. This set of three books provides a timely and comprehensive overview of the field and documents the latest research.
Building on the first and second volumes that focussed on biochemistry and bioinorganic chemistry aspects, the third volume focusses on spectroscopic and computational methods that have been applied to both enzymes and model compounds. A particular emphasis is placed on how these important studies have been used to reveal critical components of enzyme mechanisms.
This text will be a valuable reference to workers both inside and outside the field, including graduate students and young investigators interested in developing new research programs in this area.
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Detaljer om varen
- Hardback: 326 sider
- Udgiver: Royal Society of Chemistry, The (September 2016)
- Forfattere: Russ Hille, Carola Schulzke og Martin L. Kirk
- ISBN: 9781782628781
- The book will cover the bio-, inorganic and bioinorganic chemistry of molybdenum containing enzymes, including mononuclear molybdenum-containing enzymes, the complex Fe/Mo enzyme nitrogenase, and also tungsten enzymes. The full range of physicochemical methods that are used to investigate their and function will be covered.
- There has been no comprehensive book in this area for the past 30 years, despite great progress in our understanding of molybdenum enzymes and relevant inorganic complexes of molybdenum, and as a result the proposed book will both fill an enormous gap in coverage of the field and at the same time document the latest research.
- The book will be useful for workers in the field of metal-containing enzymes, graduate students and young investigators interested in developing new research programs in the area. It will also serve as a useful reference for researchers outside the field.
- Cross promotion: Journals: Dalton Transactionsand Metallomics. Books: "Iron-Containing Enzymes", Visser and Kumar, 2011; "Binding, Transport and Storage of Metal Ions in Biological Cells", Maret and Wedd, 2014.
- Cross promotion: Journals: Dalton Transactionsand Metallomics. Books: "Iron-Containing Enzymes", Visser and Kumar, 2011; "Binding, Transport and Storage of Metal Ions in Biological Cells", Maret and Wedd, 2014.
- Cross promotion: Journals: Dalton Transactionsand Metallomics. Books: "Iron-Containing Enzymes", Visser and Kumar, 2011; "Binding, Transport and Storage of Metal Ions in Biological Cells", Maret and Wedd, 2014.
- Cross promotion: Journals: Dalton Transactionsand Metallomics. Books: "Iron-Containing Enzymes", Visser and Kumar, 2011; "Binding, Transport and Storage of Metal Ions in Biological Cells", Maret and Wedd, 2014.
Part I Molybdenum- and tungsten-containing enzymes; Abundance, ubiquity, and evolution of molybdoenzymes; Molybdenum cofactor biosynthesis; Bacterial molybdoenzymes; The prokaryotic Mo/W-bisPGD enzyme family; Enzymes of the xanthine oxidase family; The sulfite oxidase family of Mo enzymes; Nitrogenase; Tungsten-containing enzymes;
Part II Introduction and overview of synthetic Mo and W chemistry; Synthesis of mono- and bisdithiolene Mo and W model compounds; Pterininspired Model Compounds of Molybdenum Enzymes; Synthesis of models for the xanthine oxidase family of enzymes; Electron transfer mechanisms in Mo and W compounds; Comparative kinetics of enzymes and models; Models of the metal clusters of nitrogenase;
Part III Overview of spectroscopic and electronic studies of Mo and W enzymes; Spectroscopic and electronic structure studies of Mo model compounds and enzymes; Electron paramagnetic resonance studies of molybdenum enzymes; X-ray absorption spectroscopy of molybdenum and tungsten Enzymes; Electrochemistry of molybdenum and tungsten enzymes; Computational studies of molybdenum and tungsten enzymes; Nitrogen Fixation in Nitrogenase and Related Small-Molecule Models